Irradiation-induced large bubble formation and grain growth in super nano-grained ceramic

In this work, 0.5TRPO•0.5Gd₂Zr₂O₇ ceramic with an average grain size of only ∼15 nm was prepared by a high pressure (5 GPa/520 °C) sintering method. Phase evolutions and microstructure changes of the as-fabricated super nano and micron-grained ceramics under a high-dose displacement damage induced by 300 keV Kr²⁺ ions were investigated. The results show that the super nano-grained ceramic has low degree of amorphization, obvious grain growth (2–3 times in grain size) and big Kr bubbles (10–68 nm) formation after irradiation. The micron-grained ceramic was severely amorphized after irradiation and many microcracks were formed parallel to its surface. The formation mechanism of Kr bubbles in the super nano-grained ceramic is on account of grain boundary diffusion and migration induced by the accumulation of the injecting Kr ions and irradiation defects. Nevertheless, microcracks formed in the micron-grained sample are caused by the accumulation of Kr atoms.     

On the Catalytic Activity of Sn Monomers and Dimers at Graphene Edges and the Synchronized Edge Dependence of Diffusing Atoms in Sn Dimers

In this study, in situ transmission electron microscopy is performed to study the interaction between single (monomer) and paired (dimer) Sn atoms at graphene edges. The results reveal that a single Sn atom can catalyze both the growth and etching of graphene by the addition and removal of C atoms respectively. Additionally, the frequencies of the energetically favorable configurations of an Sn atom at a graphene edge, calculated using density functional theory calculations, are compared with experimental observations and are found to be in good agreement. The remarkable dynamic processes of binary atoms (dimers) are also investigated and is the first such study to the best of the knowledge. Dimer diffusion along the graphene edges depends on the graphene edge termination. Atom pairs (dimers) involving an armchair configuration tend to diffuse with a synchronized shuffling (step-wise shift) action, while dimer diffusion at zigzag edge terminations show a strong propensity to collapse the dimer with each atom diffusing in opposite directions (monomer formation). Moreover, the data reveals the role of C feedstock availability on the choice a single Sn atom makes in terms of graphene growth or etching. This study advances the understanding single atom catalytic activity at graphene edges.     

Improving the fill factor of N2200-based all polymer solar cells by introducing EPPDI as a solid additive

A cheap and commercially available small molecule (namely EPPDI) is introduced to the active layer of N2200-based all polymer solar cells as a solid additive. EPPDI at the optimal ratio can improve the D-A nano-scale morphology and reduce trap density of the active layer by filling morphological spaces. As a result, the photovoltaic performance of the resulting devices based on PF2:N2200 are increased from 6.28% to 7.03% with significantly enhanced fill factor. This work demonstrates a facile approach for improving the performance of all polymer solar cells.     

基于SCA波形采样读出电子学的CSNS Back-n中子飞行时间测量

中国散裂中子源(CSNS)反角白光中子束线(Back-n)对中子核数据测量和核技术应用等多个领域均有重要意义。为监测其中子束斑轮廓、束流密度及束流能量，研制了由镀硼微网格气体(Micromegas)探测器构成的束流剖面监测装置，并通过测量中子的飞行时间(TOF)来获得能量信息。采用基于开关电容阵列(SCA)专用集成电路(ASIC)的波形采样电子学系统，实现了128路Micromegas探测器阳极条信号的低噪声放大、成形和波形数字化，在现场可编程逻辑门阵列(FPGA)芯片中实现了对信号过阈时间的实时测量，其量程为650 ns～10 ms，电子学时间分辨好于10 ns。在CSNS Back-n上开展实验，成功获得了中子束流剖面及10.65 μs～10 ms范围的飞行时间谱，对应的中子能量范围约为0.16 eV～0.14 MeV。利用钽、钴等吸收体进行了中子共振吸收峰的检验，验证了读出电子学系统的功能及飞行时间测量的正确性。     

Effect of interfacial friction force on material removal in full aperture continuous polishing process

Full aperture continuous polishing using pitch lap is a key process of finishing large flat optical workpiece. The friction force of the workpiece and pitch lap interface significantly affects material removal. In this work, the friction force was determined by a measurement system that uses force transducers to support the workpiece. Experimental and theoretical analyses have been carried out to investigate the evolution of friction force with polishing time and its effect on material removal. Our results show that the friction coefficient of the workpiece/lap interface decreases during polishing, which is due to surface smoothing of the viscoelastic pitch lap by loading conditioner. In addition, the spatial average and uniformity of material removal rate (removal coefficient) increases with the increase of friction coefficient, which is due to rough lap surface, provides more sharp asperities to charge the polishing particles.     

Assessing the energy and daylighting impacts of human behavior with window shades,a life-cycle comparison of manual and automated blinds

Manual and automated blind controls are typically not included in energy and daylight simulation in part because there is no consensus in the research or practice communities about the way users operate manual blinds or override automated blinds. In order for blind use patterns to become part of energy and daylight simulation best practices, the range of annual energy and daylighting impacts associated with blind use must be understood. This paper addresses these aspects by comparing four leading candidates of manually-controlled blinds plus two automated blind control algorithms using a high-rise office building located in Boise, ID. This study revealed that all four current “manual” blind use algorithm choices perform relatively similarly to automated systems, and surprisingly sometimes even more efficiently. LM-83 currently has the lowest average occlusion during regularly occupied hours, followed by Lightswitch-2002, while Blindswith-A and -B have the highest average occlusion. The IES-recommended manual blind algorithm resulted even in lower average blind occlusion and lighting energy consumption than automated systems. Finally, life-cycle cost analysis was calculated. The results show that the cost savings from interior automated shading system are substantial over a 30-year time horizon, when compared with common passive manual blinds ($25 versus $7.6 Net Present Value per SF glazing area).     

Sensitivity of a solid Eu(III) complex towards acetonitrile vapor: Structural and spectroscopic characterization

The Eu(III) nitrate complex of the meso- N,N′-bis(2-pyridylmethylene)-1,2-(R,S)-cyclohexanediamine ligand was synthesized and characterized by single crystal and powder X-ray diffraction. The crystal lattice of the complex is capable of absorbing and desorbing selectively acetonitrile molecules, at 293 K upon an acetonitrile vapor pressure of ∼0.1 × 10⁵ Pa. This process, which is partially reversible, can be easily followed by both powder X-ray diffraction (P-XRD) and Eu(III) luminescence spectroscopy. The acetonitrile molecule, located in the outer coordination sphere of the metal ion, does not affect the radiative transition probability of ⁵D₀ level of Eu(III) and also it does not activate further non-radiative channels from this level. On the other hand, this molecule is capable of affecting the energy position and intensities of the crystal field components of the ⁵D₀→⁷F₂ transition. The complex in solid form can be considered a promising material for the optical sensing of acetonitrile vapors.     

基于BEPCⅡ数字束流位置测量系统电子学系统的设计与实现

BEPCⅡ加速器的束流位置测量系统（BPM）模拟电子学经过十余年的运行逐渐老化，故障率上升，亟需进行升级改造。本文根据该需求，自行设计了基于BEPCⅡ系统参数的数字BPM电子学系统，内容包括模拟信号处理电子学、数字信号处理电子学、BPM固件算法逻辑、数据获取软件以及系统测试等多个部分。设计的数字BPM电子学系统经实验板级性能测试、实验室系统测试以及在线束流测试，结果表明该系统能满足BEPCⅡ装置对束流位置测量的需求。     

The effect of the exposed crystal plane on the antioxidant activity of nanoceria

Previous reports have noted that exposed crystal planes could affect the antioxidant activity of nanocerias, although the synthesized nanocerias used in those studies had different exposed crystal planes, as well as different sizes and morphologies. In order to better understand the effect of the crystal planes on the antioxidant activity of the materials, two types of nanocerias with similar morphology and size distribution but different crystal planes were synthesized using the hydrothermal method (CeO₂–H) and the ultrasonic template method (CeO₂–U). The antioxidant activities of the nanocerias were further explored within different ·OH concentrations in the reaction system. The experimental results showed that there is an obvious difference in the antioxidant activity of the two types of nanocerias in the lower free radical concentration system due to the effects of exposed crystal planes. CeO₂–U, with more active crystal planes (100), had stronger antioxidant activity. However, with the increase in the ·OH concentration in the reaction system, the difference in the antioxidant activity of the two nanocerias decreased. This research will increase our understanding of the antioxidant activity of the exposed crystal planes on nanocerias.